Pollution change and health risk assessment of cadmium in farmland soil in Shijiazhuang from 2016 to 2022
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摘要:
目的 了解石家庄市2016—2022年农田土壤镉污染情况,评估对人群健康的潜在风险,评价《河北省农村人居环境整治“三年行动”实施方案(2018—2020年)》(“三年行动”)的实施对镉污染的改善效果。 方法 选择石家庄6个项目县,每个县每年采集20份样本,并统一于每年7—8月在各县监测点处采样,采用标准限值对土壤中镉进行评价,同时采用地累积指数法和潜在生态风险指数法对其进行评估。 结果 共采集农田土壤840份,其中在2016年和2017年镉含量均值较大,主要集中在正定县和赞皇县;在“三年行动”后石家庄市平均镉污染水平总体有所降低。其中正定县、赞皇县、栾城区、藁城区和鹿泉区在实施后镉含量降低,无极县在“三年行动”后镉含量上升。 结论 石家庄市农田土壤中镉污染水平在“三年行动”后下降,表明该项目实施对降低土壤镉风险有一定效果,但仍需加强对土壤中镉污染的调查与监测,从而对潜在风险及时作出应对政策。 Abstract:Objective This study aims to clarify the situation of cadmium pollution in the agricultural soil of Shijiazhuang City from 2016-2022, evaluate potential health risks to the population, and assess the effectiveness of "the three-year initiative" in reducing cadmium pollution. Methods In six selected project counties, 20 soil samples were collected annually from each county. Samples were collected from monitoring points in each county annually between July-August. Cadmium levels in the soil were evaluated using standard limits. Additionally, the study used the geo-accumulation index method, and potential ecological risk index method to assess the situation. Results A total of 840 soil samples were collected. In 2016 and 2017, cadmium levels were relatively high, primarily concentrated in Zhengding County and Zanhuang County. After "the three-year initiative", there was a decrease in the average cadmium pollution level in Shijiazhuang City. Specifically, and cadmium levels decreased in Zhengding County, Zanhuang County, Luancheng County, Gaocheng County, and Luquan County after implementation. However, Wuji County saw a slight increase in cadmium levels. Conclusions The level of cadmium pollution in agricultural soil in Shijiazhuang City significantly decreased after the implementation of "the three-year initiative". This indicates that "the three-year initiative" had a certain effect in reducing soil cadmium risk. However, there is still a need to strengthen the investigation and monitoring of cadmium pollution in the soil to formulate timely policies to address potential risks. -
Key words:
- Farmland soil /
- Cadmium /
- Potential ecological risks
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表 1 土壤重金属污染等级划分标准
Table 1. Classification standards for soil heavy metal pollution
地累积指数(Igeo) Index of geoaccumulation (Igeo) Igeo 风险等级 Pollution levels Igeo<0 无污染 No pollution 0≤Igeo<1 轻污染 Light pollution 1≤Igeo<2 中污染 Medium pollution 2≤Igeo<3 中-重污染 Medium-Heavy pollution 3≤Igeo<4 重污染 Heavy pollution 4≤Igeo<5 重-极重污染 Heavy-Seriously polluted Igeo≥5 极重污染 Seriously polluted 潜在生态风险评价(E) Potential ecological risk index (E) E 级别 Level 风险等级 Risk levels E<40 1 轻微风险 Minor risk 40≤E<80 2 中等风险 Medium risk 80≤E<160 3 强风险 Strong risk 160≤E<320 4 很强风险 Very risky E≥320 5 极强风险 Extremely risky 表 2 2016—2022年石家庄农村土壤镉含量的描述性统计
Table 2. Descriptive statistics of cadmium content in rural soils in Shijiazhuang, 2016-2022
年份
Year最小值/(mg·kg-1)
Minimum/(mg·kg-1)最大值/(mg·kg-1)
Maximum/(mg·kg-1)平均值/(mg·kg-1)
Average/(mg·kg-1)中位数/(mg·kg-1)
Median/(mg·kg-1)偏度
Skewness峰度
Kurtosis标准差
Standard deviation变异系数/%
Coefficient of variation/%Mann-Kendall value 2016 0.005 0.990 0.213 0.130 1.563 2.333 0.184 86.3 Z=-0.300 2017 0.010 0.570 0.239 0.220 0.684 0.336 0.108 45.0 P=0.764 2018 0.040 0.440 0.140 0.119 1.520 2.978 0.069 49.5 2019 0.006 0.460 0.155 0.140 1.019 0.864 0.089 57.7 2020 0.010 0.510 0.129 0.106 1.256 2.179 0.090 69.6 2021 0.010 0.430 0.170 0.170 0.762 0.994 0.082 48.1 2022 0.007 0.780 0.198 0.189 1.970 9.669 0.098 49.6 表 3 2016—2022年各项目县土壤中镉含量的描述性统计
Table 3. Descriptive statistics of cadmium content in soil of project counties, 2016-2022
统计值 Statistic 正定县
Zhengding County栾城区
Luancheng County赞皇县
Zanhuang County无极县
Wuji County藁城区
Gaocheng County鹿泉区
Luquan County最小值/(mg·kg-1) Minimum/(mg·kg-1) 0.030 0.065 0.040 0.088 0.065 0.005 最大值/(mg·kg-1) Maximum/(mg·kg-1) 0.990 0.140 0.630 0.151 0.152 0.730 平均值/(mg·kg-1) Average/(mg·kg-1) 0.372 0.107 0.376 0.118 0.118 0.189 中位数/(mg·kg-1) Median/(mg·kg-1) 0.330 0.109 0.415 0.118 0.122 0.115 Z值 value -0.300 0.300 -1.202 2.403 -0.300 -1.202 P值 value 0.764 0.764 0.230 0.016 0.764 0.230 表 4 “三年行动”前后各项目县镉含量的比较
Table 4. Comparison of cadmium levels in project counties before and after "the three-year initiative"
项目县(实施前后)
Project county (Before and after implementation)最小值/(mg·kg-1)
Minimum/(mg·kg-1)最大值/(mg·kg-1)
Maximum/(mg·kg-1)平均值/(mg·kg-1)
Average/(mg·kg-1)中位数/(mg·kg-1)
Median/(mg·kg-1)标准差
Standard deviationt值
valueP值
value正定县 Zhengding County 1.535 0.132 实施前 Before implementation 0.030 0.990 0.298 0.220 0.196 实施后 After implementation 0.100 0.510 0.249 0.240 0.076 栾城区 Luancheng County 1.653 0.101 实施前 Before implementation 0.065 0.570 0.195 0.155 0.105 实施后 After implementation 0.030 0.451 0.163 0.143 0.100 赞皇县 Zanhuang County 8.946 <0.001 实施前 Before implementation 0.040 0.630 0.358 0.350 0.123 实施后 After implementation 0.060 0.370 0.174 0.180 0.059 无极县 Wuji County -2.294 0.024 实施前 Before implementation 0.088 0.151 0.122 0.123 0.017 实施后 After implementation 0.006 0.780 0.144 0.130 0.090 藁城区 Gaocheng County 4.683 <0.001 实施前 Before implementation 0.065 0.335 0.149 0.137 0.058 实施后 After implementation 0.033 0.220 0.102 0.085 0.051 鹿泉区 Luquan County 4.173 <0.001 实施前 Before implementation 0.005 0.730 0.235 0.240 0.169 实施后 After implementation 0.007 0.420 0.119 0.120 0.068 合计 Total 6.500 <0.001 实施前 Before implementation 0.005 0.990 0.226 0.180 0.151 实施后 After implementation 0.006 0.780 0.158 0.140 0.090 表 5 “三年行动”前后各项目县地累积指数的比较
Table 5. Comparison of the land accumulation index by project counties before and after "the three-year initiative"
项目县(实施前后)
Project county (Before and after implementation)无污染
No pollution轻污染
Light pollution中污染
Medium pollution中-重污染
Medium-heavy pollutionZ值
valueP值
value正定县 Zhengding County -0.887 0.375 实施前 Before implementation 4 19 13 4 实施后 After implementation 4 63 33 0 栾城区 Luancheng County -0.879 0.380 实施前 Before implementation 17 12 10 1 实施后 After implementation 45 39 16 0 赞皇县 Zanhuang County -8.051 <0.001 实施前 Before implementation 2 4 32 2 实施后 After implementation 24 71 5 0 无极县 Wuji county -1.663 0.096 实施前 Before implementation 30 10 0 0 实施后 After implementation 61 35 3 1 藁城区 Gaocheng County -3.696 <0.001 实施前 Before implementation 19 18 3 0 实施后 After implementation 78 22 0 0 鹿泉区 Luquan County -4.780 <0.001 实施前 Before implementation 13 10 14 3 实施后After implementation 66 31 3 0 表 6 “三年行动”前后各项目县潜在生态风险的比较
Table 6. Comparison of potential ecological risks in project counties before and after "the three-year initiative"
项目县(实施前后)
Project county (Before and after implementation)轻微风险
Minor risk中等风险
Medium risk强风险
Strong risk很强风险
Very risky极强风险
Extremely riskyZ值
valueP值
value正定县 Zhengding County -0.288 0.774 实施前 Before implementation 4 18 10 7 1 实施后 Afterimplementation 2 43 54 1 0 栾城区 Luancheng County -2.073 0.038 实施前 Before implementation 12 12 15 1 0 实施后 Afterimplementation 41 39 20 0 0 赞皇县 Zanhuang County -7.490 <0.001 实施前 Before implementation 2 3 27 8 0 实施后 Afterimplementation 16 70 14 0 0 无极县 Wuji County -0.401 0.688 实施前 Before implementation 18 22 0 0 0 实施后 Afterimplementation 45 48 6 1 0 藁城区 Gaocheng County -4.878 <0.001 实施前 Before implementation 12 25 3 0 0 实施后 Afterimplementation 73 27 0 0 0 鹿泉区 Luquan County -4.293 <0.001 实施前 Before implementation 12 7 17 4 0 实施后 Afterimplementation 47 50 3 0 0 -
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